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RTP (Rubidium Titanyl Phosphate)

RTP (Rubidium Titanyl Phosphate)RTP, which has only recently become commercially available, is the material of choice for many NLO and electrooptic applications. It’s high optical damage threshold makes it especially useful in high power SHG and OPO applications. RTP’s high electrical resistivity is important for many electrooptic applications, and in the production of Periodically Poled RTP elements.

RTP vs. KTP Comparison Chart

Property KTP RTP
Type II SHG at 1064 nm
Phase matchable range (nm) 980-1080 1050-1140
Nonlinear coefficients (pm/V)
 d33 16.9 17.1
 d31 2.5 3.3
 d32 4.4 4.1
 deff 3.34 2.45
Phase matching angle (deg) 22-25 58
Walk-off angle (deg) 0.26 0.4
Angular acceptance (mrad cm) 20 20
Temperature acceptance (℃ cm) 25 40
Transparency range (nm) 350-4500 350-4500
Other Properties   
Wavelength of noncritical OPO 1064nm (nm) 1570/3300 1600/3200
Electro optical coefficients (pm/V)
 r33 36.3 39.6
 r13 9.5 12.5
 r23 15.7 17.1
Dielectric constant εeff 13 13
Optical damage ratio (to KTP) 1 1.8
Electrical conductivity along Z axis (Ω-1 cm-1) 10-6-10-7 10-11-10-12
Pyroelectric coefficient (C/cm2 K) 7 × 10-9 4 × 10-9

EO結晶の比較表 Comparison of Electrooptic Materials

Property Units RTP KD*P LiNbO3 LiTaO3 BBO KTP RTA
Transparency
range
µm 0.35-4.3 0.2-2.15 0.35-5.5 0.3-5.5 0.19-2.6 0.35-4.3 0.35-5.3
Refractive
index
  1.9 1.5 2.2 2.2 1.6 1.9 1.9
Vλ/2 (1064nm)
(L=d) - static
kV 8* 9 8.5 5 46 8* 8*
Temperature
coefficient
of Vλ/2
%/℃ small large small small 0.1 small small
Dielectric
constant,ε
  11 48 27.9 45 6.7 15.4 11
Laser damage
threshold
(AR coated)
MW/cm2 600 500 280 400 1000 600 400
Conductivity,
σ33
S/cm ~10-11 <10-12 <10-12 <10-12 <10-12 <10-6 <10-9
Optical
Homogeneity
  good excellent fair fair excellent good good
Acoustic
ringing 
  no yes yes no small no no
Temperature
stability
  good problem problem good good good good
Hygroscopic no yes no no slight no no
 * Vλ/2 measured for light propagating in the x direction

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