Yttrium Vanadate(YVO4) is a positive uniaxial crystal grown with Czochralski method.
It has good temperature stability and physical and mechanical properties.
It is ideal for optical polarizing components because of its wide transparency range and large birefringence.
It is an excellent synthetic substitute for Calcite (CaCO3) and Rutile (TiO2) crystals in many applications including fiber optic isolators and circulators, interleavers, beam displacers and other polarizing optics

Comparison of basic properties between YVO4 and Other Birefringent Crystals.

YVO4 TiO2 CaCO3 LiNbO3
Thermal
Expansion(/℃)
c-axis: 11.4 x 10-6,a-axis: 4.4 x 10-6 c-axis: 9.2 x 10-6,a-axis: 7.1 x 10-6 c-axis: 26.3 x 10-6,a-axis: 5.4 x 10-6 c-axis: 16.7 x 10-6,a-axis: 7 x 10-6
Refractive Index no: 1.9447@1550nm,ne: 2.1486@1550nm no: 2.454@1530nm,ne: 2.710@1530nm no: 1.6346@1497nm,ne: 1.4774@1497nm no: 2.2151@1440nm,ne: 2.1413@1440nm
Birefringence(ne-no) 0.2039@1550nm 0.256@1530nm -0.1572@1497nm -0.0738@1440nm
Mohs Hardness 5 6.5 3 5
Deliquescence None None Weak None
Transparency range 0.4-5 µm 0.4-5 µm 0.35-2.3 µm 0.4-5 µm

A reliable supplier of YVO4 crystal

CASTECH is one of the earliest companies who devotes to research and have mastered the advanced growth technique of YVO4 crystal. Now CASTECH has completed its strong mass-production line that can provied:

  • Various size bulk and finished high quality YVO4 crystals up to φ35x50mm3 and φ20x20mm3, respectively;
  • Large quantity YVO4 wedges and displacers used for fiber optical isolators and circulators, interleavers, in size 1.25×1.25×0.5mm to 3×3×15mm to meet OEM customer’s requirement.
  • Quick delivery
  • Very competitive price
  • Strict quality control;
  • Very competitive price

Basic Properties of YVO4 crystal

Transparency Range: High transmittance from 0.4 to 5 µm
Crystal Symmetry: Zircon Tetragonal, space group D4h
crystal Cell: a=b=7.12 A;c=6.29 A
Density: 4.22 g/cm3
Mohs Hardness: 5, glass-like
Hygroscopic Susceptibility: Non-hygroscopic
Thermal Expansion Coefficiet: αa=4.43 x 10-6/K; αc=11.37 x 10-6/K
Thermal Conductivity Coefficient: //C:5.23 W/m/K; ⊥C:5.10 W/m/K
Crystal Class: Positive uniaxial with no=na=nb,ne=nc
Thermal Optical Coefficient: Dna/dT=8.5x10-6/K;dnc/dT=3.0x10-6/K
Refractive Indices, Birefringence
(△n=ne-no)
and Walk-off Angle at 45°(ρ):
no=1.9929,ne=2.2154,△n=0.2225,ρ=6.04° at 630 nm
no=1.9500,ne=2.1554,△n=0.2054,ρ=5.72° at 1300 nm
no=1.9447,ne=2.1486,△n=0.2039,ρ=5.69° at 1550 nm
Sellmeier Equation (λ in µm): no2=3.77834+0.069736/(λ2-0.04724)-0.0108133λ2
ne2=4.59905+0.110534/(λ2-0.04813)-0.0122676λ2

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