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Nd:GdVO4 レーザ結晶

Neodymium Doped Gadolinium Orthovanadate(Nd:GdVO4)

CASTECH’s Nd:GdVO4 is featured by

Nd:YVO4 レーザ結晶
  • Large stimulated emission cross section at laser wavelength;
  • High absorption coefficient and wide bandwidth at pump wavelength;
  • Low dependency on pump wavelength;
  • Good thermal conductivity;
  • Low lasing threshold and high slope efficiency;
  • High laser induced damage threshold;
  • Strongly-polarized laser output.

仕様

Crystal structure  Tetragona
Space Group  I41/amd
Lattice paramete  a=0.721nm, b=0.635nm
Lasing Transition 4F3/2 → 4I11/2
Lasing wavelength  1062.9nm
Emission Cross Section (at 1064nm)  7.6x10-19 cm2
Absorption Cross Section (at 808nm)  4.9x10-19  cm2
Absorption Coefficient (at 808nm)  74cm-1
Index of Refractivity (at 1064nm)  n0=1.972,   ne=2.192
Thermal Conductivity (<110>)  11.7W/(mxK)
Density  5.47g/cm3
Nd Dopent level (atomic)  0.1%, 0.2%, 0.3%, 0.5%, 0.7%, 1.0%...

Information Regarding Neodymium Laser Host Crystals

Crystal Nd:YVO4 Nd:GdVO4 Nd:YAG
Laser wavelengths 1064.3nm,1342.0nm 1062.9nm,1340nm 1064.2nm,1338.2nm
Emission bandwidth (linewidth at 1064nm) 0.8nm No dara 0.45nm
Effective laser cross section (emission cross section at 1064nm) 15.6x10-19cm2 7.6x10-19cm2 6.5x10-10cm2
Polarization Parallel to c-axis Parallel to c-axis unpolarized
Radioactive lifetime (microseconds) at 1% Nd doping ~100µs ~95µs 230µs
Pump wavelength 808.5nm 808.4nm 807.5nm
Peak pump absorption at 1% doping ~ 41 cm-1 ~ 57 cm-1  
Thermal conductivity, W/nK 5.1 11.7(Ref.7) 14
Doping concentration range 0.1~3.0% 0.1~3.0% 0.1~2.0%

Material Properties:Comparing Nd:GdVO4 and Nd:YVO4

Crystal Nd:GdVO4 Nd:YVO4
Crystal Structure,Space Group Tetragonal,141/amd tetragonal,141/amd
Lattice constants,nm a:0.721     b:0.635 a:0.721     b:0.629
Melting temperature,℃ 1780 1825
Thermal expansion@25℃, X10-6/℃ a 1.5 a 4.43
b 7.3 b 11.4
Specific heat@25℃,cal/mol K 32.6 24.6
dn/dT, x10-6/℃ 4.7 2.7

CASTECH Warranty on Nd:GdVO4 Specifications

  • Transmitting wavefront distortion:less than λ/4 @ 633nm
  • Dimension tolerance:(W±0.1mm)x(H±0.1mm)x(L+0.2mm/-0.1)
  • Clear aperture:>90% central area
  • Flatness: λ/8 @ 633 nm, and λ/4 @ 633nm for thickness less than 2mm
  • Scratch/Dig code: 10/5 to MIL-PRF-13830B
  • Parallelism:better than 20 arc seconds
  • Perpendicularity: 5 arc minutes
  • Angle tolerance:<±0.5°
  • AR coating: R<0.2% at 1064nm
  • HR coating:R>99.8%@1064nm,T>95%@808nm
  • Quality Warranty Period:one year under proper use.

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