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Cr:LiSAF レーザ結晶

Cr-doped Colquiriite-Cr:LiSAF

Cr:LiSAF レーザ結晶CASTECH provides high quality, Cr-doped colquiriite crystals(Cr:LiSAF) using the Czochralski technique. This family of materials includes LiSAF, LiSGaF and LiCAF. They are excellent laser materials with high energy storage and high slope efficiency. They are also ideal working materials under conditions of ultra short pulse and ultra high power. Currently, Cr:LiSAF related products such as flashlight pumping and semi-conductor pumping laser have been widely used.

Physical Properties

Chemical Formula Cr3+:LiSrAlF6
Lattice Parameters(Å) a=5.084
c=10.21
Crystal structure trigonal
Space Group P31c
Cr atoms/cm3 for 1% doping 8.75x1019
Fracture Toughness(Mpam) 0.40( || c)
Melting Point (℃) 766
Density(g/ cm³) 3.45
Modulus of Elasticity(GPa) 109
Thermal Expansion -10( || c)
Coefficient (106K) 25(┴c)
Thermal Conductivity (W/m/K) 3.3( || c)
3.0(┴c)
Specific Heat(J/gK) (@25℃) 0.842

Optical Properties

Emission Peak(nm) 846
Peak Stimulated Emission Cross Section(×10-20cm2) 4.8( || c)
Spontaneous Fluorescence Lifetime(µs) 67
Scatter Losses(%/cm) <0.2
dn/dT(×10-6 ℃)  -4.8( || c)
-2.5(┴c)

The Sellmeier equations(l in mm):

  nc2 =1.98448+0.00235/(λ²-0.010936)-0.01057λ²
  na2=1.97673+0.00309/(λ²-0.00935)-0.00828λ²

Crystal Wavelength(nm) nc na
Cr:LiSAF 846 1.407 1.405 
670 1.409 1.407
423 1.413 1.412
290 1.420 1.420
266 1.422 1.424

Specifications of Cr:LiSAF

  • Size: Rod sizes from 2mm to 16mm in diameter and from 1mm to 180mm in length
  • Cr dopant concentrations: 0.5~1.0 mol%
  • Parallelism: <10 arc seconds
  • Perpendicularity: <5 arc minutes
  • Chamfer: 0.13±0.07mm @ 45°
  • Scratch/Dig code: 10/5 to MIL-PRF-13830B
  • Flatness: λ/8 @ 632.8nm
  • AR coating: R<0.10% @ 850nm

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